High Specific Power Dual-Metal-Ion Rechargeable Microbatteries Based on LiMn2O4 and Zinc for Miniaturized Applications
Miniaturized rechargeable batteries with high specific power are required for substitution of the large sized primary batteries currently prevalent in integrated systems since important implications in dimensions and power are expected in future miniaturized applications. Commercially available secondary microbatteries are based on lithium metal which suffers from several well-known safety and manufacturing issues and low specific power when compared to (super) capacitors. A high specific power and novel dual-metal-ion microbattery based on LiMn2O4, zinc, and an aqueous electrolyte is presented in this work. Specific power densities similar to the ones exhibited by typical electrochemical supercapacitors (3400 W kg–1) while maintaining specific energies in the range of typical Li-ion batteries are measured (∼100 Wh kg–1). Excellent stability with very limited degradation (99.94% capacity retention per cycle) after 300 cycles is also presented. All of these features, together with the intrinsically safe nature of the technology, allow anticipation of this alternative micro power source to have high impact, particularly in the high demand field of newly miniaturized applications.
Jon Fold von Bülow
Jon Fold von Bülow recieved his Cand. Scient. in Nanoscience from University of Copenhagen in 2011 and is currently working with upscaling Li- and Na-ion battery materials to the 100+ kg scale for Haldor Topsøe A/S.
Jon's main interest lies in energy technologies for the future and he started working with fusion energy at Risø National Laboratory for Sustainable Energy. He has since developed a growing interest in technologies that are closer to potential industrial application. He is a highly dedicated academic as well as a very active professional and have initiated and participated in many different projects.
His studies within nanotechnological material science and affiliation with Risø National Laboratories has taken him to Germany, China and the US, where he has collaborated independently with several international research groups. He has so far succeeded in pushing two academic projects to industrial application, first with the Danish company Coloplast A/S and recently with a California-based battery start-up – an invention that is currently being US patented.
Jon has conducted most of his work on Li-batteries in the facilities of California NanoSystems Institute (CNSI) as a research scholar at UCSB-MIT-Caltech Institute for Collaborative Biotechnologies (ICB). The manganese based cathode materials he fabricated during this period were all tuned for high-power applications and covers synthesis of various manganese oxides from solution, molten and solid states.
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